Peroxide-Templated Assembly of a Trimetal Neodymium Complex Single-Molecule Magnet

Justin T. Miller, Yixin Ren, Sheng Li, Kui Tan, Gregory McCandless, Christine Jacob, Zheng Wu, Ching Wu Chu, Bing Lv, Michael C. Biewer, Mihaela C. Stefan

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5 引文 斯高帕斯(Scopus)

摘要

In this work, we present a trimetal neodymium complex with two notable qualities. First, the assembly of the complex is templated by peroxide derived from atmospheric oxygen. Second, the bulk material behaves as a superparamagnet, implying that the individual complexes are molecular magnets. Peroxide-templated assembly is possible because of the confluence of the high oxophilicity of neodymium along with the use of an azeotropic distillation synthesis method, which excludes water but admits oxygen. SQUID magnetometry measurements show an extremely high magnetic susceptibility as well as a lack of remanence.

原文English
頁(從 - 到)10379-10383
頁數5
期刊Inorganic Chemistry
59
發行號15
DOIs
出版狀態Published - 2020 8月 3

All Science Journal Classification (ASJC) codes

  • 物理與理論化學
  • 無機化學

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