@article{4edbe573148b4626babc07aef5a24841,
title = "Peroxide-Templated Assembly of a Trimetal Neodymium Complex Single-Molecule Magnet",
abstract = "In this work, we present a trimetal neodymium complex with two notable qualities. First, the assembly of the complex is templated by peroxide derived from atmospheric oxygen. Second, the bulk material behaves as a superparamagnet, implying that the individual complexes are molecular magnets. Peroxide-templated assembly is possible because of the confluence of the high oxophilicity of neodymium along with the use of an azeotropic distillation synthesis method, which excludes water but admits oxygen. SQUID magnetometry measurements show an extremely high magnetic susceptibility as well as a lack of remanence. ",
author = "Miller, {Justin T.} and Yixin Ren and Sheng Li and Kui Tan and Gregory McCandless and Christine Jacob and Zheng Wu and Chu, {Ching Wu} and Bing Lv and Biewer, {Michael C.} and Stefan, {Mihaela C.}",
note = "Funding Information: We gratefully acknowledgefinancial support from the National Science Foundation (Grant CHE-1566059), Welch Foundation (Grant AT-1740), and Air Force Office of Scientific Research (Grants FA9550-15-1-0236 and FA9550-19-1-0037). M.C.S. acknowledges generous financial support from the Eugene McDermott Foundation. This project is also partially funded by The University of Texas at Dallas Office of Research through the Core Facility Voucher Program. We thank Yves Chabal and the Materials and Surface Technology Resource for XPS and Raman spectroscopic data collection. The XPS and Raman spectroscopic characterization and analysis were supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, under Award DE-SC0019902. Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",
year = "2020",
month = aug,
day = "3",
doi = "10.1021/acs.inorgchem.0c00234",
language = "English",
volume = "59",
pages = "10379--10383",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "15",
}