Peroxide-Templated Assembly of a Trimetal Neodymium Complex Single-Molecule Magnet

Justin T. Miller; Yixin Ren; Sheng Li; Kui Tan; Gregory McCandless; Christine Jacob; Zheng Wu; Ching Wu Chu; Bing Lv; Michael C. Biewer; Mihaela C. Stefan

doi:10.1021/acs.inorgchem.0c00234

Peroxide-Templated Assembly of a Trimetal Neodymium Complex Single-Molecule Magnet

Justin T. Miller, Yixin Ren, Sheng Li, Kui Tan, Gregory McCandless, Christine Jacob, Zheng Wu, Ching Wu Chu, Bing Lv, Michael C. Biewer, Mihaela C. Stefan

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8 引文斯高帕斯（Scopus）

摘要

In this work, we present a trimetal neodymium complex with two notable qualities. First, the assembly of the complex is templated by peroxide derived from atmospheric oxygen. Second, the bulk material behaves as a superparamagnet, implying that the individual complexes are molecular magnets. Peroxide-templated assembly is possible because of the confluence of the high oxophilicity of neodymium along with the use of an azeotropic distillation synthesis method, which excludes water but admits oxygen. SQUID magnetometry measurements show an extremely high magnetic susceptibility as well as a lack of remanence.

原文	English
頁（從 - 到）	10379-10383
頁數	5
期刊	Inorganic Chemistry
卷	59
發行號	15
DOIs	https://doi.org/10.1021/acs.inorgchem.0c00234
出版狀態	Published - 2020 8月 3

All Science Journal Classification (ASJC) codes

物理與理論化學
無機化學

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10.1021/acs.inorgchem.0c00234

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引用此

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abstract = "In this work, we present a trimetal neodymium complex with two notable qualities. First, the assembly of the complex is templated by peroxide derived from atmospheric oxygen. Second, the bulk material behaves as a superparamagnet, implying that the individual complexes are molecular magnets. Peroxide-templated assembly is possible because of the confluence of the high oxophilicity of neodymium along with the use of an azeotropic distillation synthesis method, which excludes water but admits oxygen. SQUID magnetometry measurements show an extremely high magnetic susceptibility as well as a lack of remanence.",

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AU - Miller, Justin T.

AU - Ren, Yixin

AU - Li, Sheng

AU - Tan, Kui

AU - McCandless, Gregory

AU - Jacob, Christine

AU - Wu, Zheng

AU - Chu, Ching Wu

AU - Lv, Bing

AU - Biewer, Michael C.

AU - Stefan, Mihaela C.

PY - 2020/8/3

Y1 - 2020/8/3

N2 - In this work, we present a trimetal neodymium complex with two notable qualities. First, the assembly of the complex is templated by peroxide derived from atmospheric oxygen. Second, the bulk material behaves as a superparamagnet, implying that the individual complexes are molecular magnets. Peroxide-templated assembly is possible because of the confluence of the high oxophilicity of neodymium along with the use of an azeotropic distillation synthesis method, which excludes water but admits oxygen. SQUID magnetometry measurements show an extremely high magnetic susceptibility as well as a lack of remanence.

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JO - Inorganic Chemistry

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Peroxide-Templated Assembly of a Trimetal Neodymium Complex Single-Molecule Magnet

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