Preparation and characterization of interconnected carbon nanofibers

ya Hui Hsu, Ching Chang Lai, yi te Peng, Chieh Tsung lo

研究成果: Article同行評審

5 引文 斯高帕斯(Scopus)

摘要

A strategy to prepare interconnected carbon nanofibers using an electrospinning technique is proposed. This strategy lies in the addition of poly(acrylonitrile-co-butadiene (PAN-co-PB) copolymer in a precursor solution composed of polyacrylonitrile (PAN) and N,N-dimethylformamide. During pyrolysis, PB decomposed, softening the fibers and creating the possibility of fiber–fiber connection. The fiber diameter decreased with an increase in the PAN-co-PB content. Further addition of PAN-co-PB caused the fusion of neighboring fibers, which enlarged the fiber diameter and decreased the specific surface area of fibers. The microcrystallite sizes of carbon nanofibers depended on the PAN-co-PB content; and the addition of PAN-co-PB promoted the development of ordered graphite crystallites. The interconnected carbon nanofibers exhibited an electrical conductivity four times larger than that of the nanofibers with a uniform separated fibrous structure. The purpose of this work is to prepare carbon nanofiber mats with good electrical conductivity and well-controlled morphology for further use as energy-associated devices and catalyst supports.

原文English
頁(從 - 到)3-12
頁數10
期刊Textile Research Journal
85
發行號1
DOIs
出版狀態Published - 2015 一月

All Science Journal Classification (ASJC) codes

  • Chemical Engineering (miscellaneous)
  • Polymers and Plastics

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