Preparation, Crystallization Behavior, and Morphology of Poly(lactic acid) Clay Hybrids via Wet Kneading Masterbatch Process

Chi Yuan Hung, Deng Ke Huang, Cheng Chien Wang, Chuh-Yung Chen

研究成果: Article

4 引文 (Scopus)

摘要

Modified masterbatch method comprising of the wet kneading and intercalated modifiers process was successfully applied to prepare exfoliated polylactic acid (PLA) clay hybrids. The crystallization rate of PLA/clay nanocomposite was improved by introducing alkylamide, an intercalated modifier with higher crystallinity. Both XRD and TEM analyses showed that the exfoliated and partially intercalated PLA nanocomposites can be obtained. The effect of clay and intercalated modifier on the nonisothermal, isothermal crystallization kinetics, and morphology of PLA was investigated using DSC instrument. The PLA nanocomposites showed faster crystallization rate because the alkylamide modifier act as a nucleation agent that successfully promoted crystallization. Notably, the crystallinity of PLA/clay hybrids dramatically increased from 9.0 to 42.1 %. The nucleation and crystal growth rate of PLA when crystallized from melt state is greatly influenced by the presence of organoclays. Therefore, as revealed from this isothermal crystallization investigation, the crystallization rate is enhanced by a factor of about 7-17.

原文English
頁(從 - 到)1389-1396
頁數8
期刊Journal of Inorganic and Organometallic Polymers and Materials
23
發行號6
DOIs
出版狀態Published - 2013 十一月 1

指紋

Lactic acid
Crystallization
Clay
Acids
Nanocomposites
Nucleation
Organoclay
Crystallization kinetics
poly(lactic acid)
clay
Crystal growth
Transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

引用此文

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title = "Preparation, Crystallization Behavior, and Morphology of Poly(lactic acid) Clay Hybrids via Wet Kneading Masterbatch Process",
abstract = "Modified masterbatch method comprising of the wet kneading and intercalated modifiers process was successfully applied to prepare exfoliated polylactic acid (PLA) clay hybrids. The crystallization rate of PLA/clay nanocomposite was improved by introducing alkylamide, an intercalated modifier with higher crystallinity. Both XRD and TEM analyses showed that the exfoliated and partially intercalated PLA nanocomposites can be obtained. The effect of clay and intercalated modifier on the nonisothermal, isothermal crystallization kinetics, and morphology of PLA was investigated using DSC instrument. The PLA nanocomposites showed faster crystallization rate because the alkylamide modifier act as a nucleation agent that successfully promoted crystallization. Notably, the crystallinity of PLA/clay hybrids dramatically increased from 9.0 to 42.1 {\%}. The nucleation and crystal growth rate of PLA when crystallized from melt state is greatly influenced by the presence of organoclays. Therefore, as revealed from this isothermal crystallization investigation, the crystallization rate is enhanced by a factor of about 7-17.",
author = "Hung, {Chi Yuan} and Huang, {Deng Ke} and Wang, {Cheng Chien} and Chuh-Yung Chen",
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T1 - Preparation, Crystallization Behavior, and Morphology of Poly(lactic acid) Clay Hybrids via Wet Kneading Masterbatch Process

AU - Hung, Chi Yuan

AU - Huang, Deng Ke

AU - Wang, Cheng Chien

AU - Chen, Chuh-Yung

PY - 2013/11/1

Y1 - 2013/11/1

N2 - Modified masterbatch method comprising of the wet kneading and intercalated modifiers process was successfully applied to prepare exfoliated polylactic acid (PLA) clay hybrids. The crystallization rate of PLA/clay nanocomposite was improved by introducing alkylamide, an intercalated modifier with higher crystallinity. Both XRD and TEM analyses showed that the exfoliated and partially intercalated PLA nanocomposites can be obtained. The effect of clay and intercalated modifier on the nonisothermal, isothermal crystallization kinetics, and morphology of PLA was investigated using DSC instrument. The PLA nanocomposites showed faster crystallization rate because the alkylamide modifier act as a nucleation agent that successfully promoted crystallization. Notably, the crystallinity of PLA/clay hybrids dramatically increased from 9.0 to 42.1 %. The nucleation and crystal growth rate of PLA when crystallized from melt state is greatly influenced by the presence of organoclays. Therefore, as revealed from this isothermal crystallization investigation, the crystallization rate is enhanced by a factor of about 7-17.

AB - Modified masterbatch method comprising of the wet kneading and intercalated modifiers process was successfully applied to prepare exfoliated polylactic acid (PLA) clay hybrids. The crystallization rate of PLA/clay nanocomposite was improved by introducing alkylamide, an intercalated modifier with higher crystallinity. Both XRD and TEM analyses showed that the exfoliated and partially intercalated PLA nanocomposites can be obtained. The effect of clay and intercalated modifier on the nonisothermal, isothermal crystallization kinetics, and morphology of PLA was investigated using DSC instrument. The PLA nanocomposites showed faster crystallization rate because the alkylamide modifier act as a nucleation agent that successfully promoted crystallization. Notably, the crystallinity of PLA/clay hybrids dramatically increased from 9.0 to 42.1 %. The nucleation and crystal growth rate of PLA when crystallized from melt state is greatly influenced by the presence of organoclays. Therefore, as revealed from this isothermal crystallization investigation, the crystallization rate is enhanced by a factor of about 7-17.

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