Pyrolysis of spill oils adsorbed on zeolites with product oils recycling

Chun Kuo Tsai, Chang Yu Liao, H. Paul Wang, Yi Chi Chien, Chih Ju G. Jou

研究成果: Article同行評審

22 引文 斯高帕斯(Scopus)

摘要

Experimentally, a feasibility study for adsorption and catalytic pyrolysis of spill oils on Cu/ZSM-5 for recycling of light oils has been conducted in the present work. The adsorption and pyrolysis of model compounds such as heptane, toluene, and diesel (to stimulate the spill oils) on Cu/ZSM-5 have been investigated on a continuous fixed-bed reactor. By component fitted X-ray absorption near edge structural (XANES) spectroscopy, catalytic active species such as metallic copper (Cu) (77-84%) and Cu2O (6-7%) are found in the channels of ZSM-5 during pyrolysis of heptane or toluene. Pyrolysis of diesel effected by Cu/ZSM-5 yields gas (C1-C5) (32%) and light oil (68%) that can be used as auxiliary fuels.

原文English
頁(從 - 到)895-898
頁數4
期刊Marine Pollution Bulletin
57
發行號6-12
DOIs
出版狀態Published - 2008 4月 7

All Science Journal Classification (ASJC) codes

  • 海洋學
  • 海洋科學
  • 污染

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