Rational design and synthesis of molecular-sieving, photocatalytic, hollow fiber membranes for advanced water treatment applications

David K. Wang, Muthia Elma, Julius Motuzas, Wen Che Hou, Fengwei Xie, Xiwang Zhang

研究成果: Article同行評審

23 引文 斯高帕斯(Scopus)

摘要

Photocatalytic, hollow fiber membranes based on nanocomposites of titania nanoparticles and carbonaceous char were simultaneously fabricated in a single calcination step, and then optimized for the photo-degradation of pollutants and water recovery in an integrated membrane operation in this study. The physicochemical, mechanical and photocatalytic properties along with separation performance of two series of membranes were finely-tuned by systematically changing the calcination temperature (series 1: 500–1000 °C for 8 h holding time) and calcination time (series 2: 2–8 h at 600 °C). The calcined membranes were extensively characterized for morphology, thermal stability, microstructure, modulus and chemical compositions. Both constituents of titania and char are essential in deriving the desirable hollow fiber properties and membrane performance for photocatalysis and water recovery. By controlling the calcination conditions, membranes prepared at 600 °C for the 3 and 6 h duration displayed an optimal balance between enhanced mechanical strength (34 MPa) and high photo-degradation of acid orange 7 (90.4%). Membrane performance demonstrated water fluxes of 6.9 (H2O/dark), 12.9 (H2O/UV) 4.8 (AO7/dark) and 7.9 L m–2 h–1 (AO7/UV) with excellent organic dye rejection. Both membranes exhibited photo-induced super-hydrophilicity and defouling potential under the influence of UV light due to the photo-activation of exposed TiO2 nanoparticles on the membrane surface. The detailed mechanism of property correlation and separation performance for the photocatalytic hollow fibers is proposed and elucidated. This work offers an innovative material for the research avenue of photocatalytic, hollow fiber membrane reactors for advanced membrane treatment applications.

原文English
頁(從 - 到)163-173
頁數11
期刊Journal of Membrane Science
524
DOIs
出版狀態Published - 2017 二月 15

All Science Journal Classification (ASJC) codes

  • 生物化學
  • 材料科學(全部)
  • 物理與理論化學
  • 篩選和分離

指紋

深入研究「Rational design and synthesis of molecular-sieving, photocatalytic, hollow fiber membranes for advanced water treatment applications」主題。共同形成了獨特的指紋。

引用此