Rheological and conductivity percolations of syndiotactic polystyrene composites filled with graphene nanosheets and carbon nanotubes: A comparative study

Yen Chang Chiu, Chien Lin Huang, Chi Wang

研究成果: Article同行評審

24 引文 斯高帕斯(Scopus)

摘要

Two-dimensional graphene nanosheets (GNSs) and one-dimensional carbon nanotubes (CNTs) possess large aspect ratios but different geometries. In this study, syndiotactic polystyrene (sPS) composites reinforced with different contents of GNSs were prepared via a solution coagulation method. The dispersion and microstructure of GNSs in sPS were confirmed via transmission electron microscopy and atomic force microscopy. Rheological and electrical properties of sPS/GNS composites were investigated to reveal the effect of filler concentration, and the results were compared with those of sPS/CNT composites. Percolation scaling laws were applied to the magnitudes of storage modulus and electrical conductivity to determine the threshold concentration and corresponding exponent. The sPS/GNS and sPS/CNT composites possess a similar percolation threshold for melt elasticity and solid conductivity. However, the rheological threshold (∼0.1 vol%) is distinctly lower than the conductivity threshold (∼0.5 vol%) because of the formation of polymer–nanofiller hybrid network. The exponents for rheological and electrical percolations of sPS/GNS composites are determined as 4.12 and 4.71, respectively, which are higher than the corresponding values of 2.64 and 2.87 for sPS/CNT composites. The derived exponents indicate that the 2D GNS-related network is more effective than the 1D CNT-related network for enhancing the melt elasticity and solid conductivity of sPS matrix.

原文English
頁(從 - 到)153-160
頁數8
期刊Composites Science and Technology
134
DOIs
出版狀態Published - 2016 十月 6

All Science Journal Classification (ASJC) codes

  • 陶瓷和複合材料
  • 工程 (全部)

指紋

深入研究「Rheological and conductivity percolations of syndiotactic polystyrene composites filled with graphene nanosheets and carbon nanotubes: A comparative study」主題。共同形成了獨特的指紋。

引用此