Salts of the two-coordinate homoleptic manganese(i) dialkyl anion [Mn{C(SiMe3)3}2]- with quenched orbital magnetism

C. Y. Lin, J. C. Fettinger, N. F. Chilton, A. Formanuik, F. Grandjean, G. J. Long, P. P. Power

研究成果: Article同行評審

16 引文 斯高帕斯(Scopus)

摘要

The reduction of Mn{C(SiMe3)3}2 with KC8 in the presence of crown ethers yielded the d6, Mn(i) salts [K2(18-crown-6)3][Mn{C(SiMe3)3}2]2 and [K(15-crown-5)2][Mn{C(SiMe3)3}2], that have near-linear manganese coordination but almost completely quenched orbital magnetism as a result of 4s-3dz2 orbital mixing which affords a non-degenerate ground state.

原文English
頁(從 - 到)13275-13278
頁數4
期刊Chemical Communications
51
發行號68
DOIs
出版狀態Published - 2015 7月 5

All Science Journal Classification (ASJC) codes

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 一般化學
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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