Single‐Crystal X‐Ray Structure of the Metastable Aryne Precursor Tetrafluorophenyllithium and of 1,2,3,4‐Tetrafluorobenzene

Thomas Kottke, Kuangsen Sung, Richad J. Lagow

研究成果: Article

26 引文 斯高帕斯(Scopus)

摘要

Do intramolecular LiF interactions affect the reactivity of aryne precursors? This was the key question for structural studies of lithiated and nonlithiated tetrafluorobenzene. No correlation between LiF distances and the ease of LiF elimination exists, and the lengths of the CarylF bonds in the lithiated compound are less affected by LiF interactions than by the “anionic” character of the benzene ring.

原文English
頁(從 - 到)1517-1519
頁數3
期刊Angewandte Chemie International Edition in English
34
發行號13-14
DOIs
出版狀態Published - 1995 七月 31

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

指紋 深入研究「Single‐Crystal X‐Ray Structure of the Metastable Aryne Precursor Tetrafluorophenyllithium and of 1,2,3,4‐Tetrafluorobenzene」主題。共同形成了獨特的指紋。

  • 引用此