SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution

Yu Jen Shih, Chia Chi Su, Yao Hui Huang, Ming Chun Lu

研究成果: Article同行評審

45 引文 斯高帕斯(Scopus)

摘要

Ferromagnetic elements Fe, Ni and Co were immobilized on the porous SiO2 to catalyze the hydrogen generation from aqueous alkaline NaBH4 (sodium borohydride). The porous SiO2 was prepared by silica-surfactant self-assembly and the ferromagnetic catalyst was prepared by chemical reduction. The ferromagnetic catalysts were characterized using TG/DTA (Thermogravimetry/differential thermal analysis), BET, XRD (X-ray powder diffraction), ESEM/EDS (environmental scanning electron microscope/energy dispersive spectroscopy), XPS (x-ray photoelectron spectroscopy) and VSM (vibration sample magnetometer) measurements. The surface area of porous SiO2 was affected by the molecular weight of surfactant. The relative catalytic activities in the generation of hydrogen from alkaline NaBH4 solution follow the order Co/SiO2 > Ni/SiO2 > Fe/SiO2. The rates of hydrogen generation using Co/SiO2, Ni/SiO2 and Fe/SiO2 catalysts in 20 ml of 5 wt.% NaBH4 solution at 313 K were 8701, 307 and 130 ml min-1 g-1-metal, respectively. It is found that the degree of metal-oxidation and crystal structure affected the catalytic activity. The hydrogen generation of NaBH4 in alkaline solution increased with increasing cobalt loading, of which the activation energy was 59 ± 2 kJ mol-1.

原文English
頁(從 - 到)263-270
頁數8
期刊Energy
54
DOIs
出版狀態Published - 2013 六月 1

All Science Journal Classification (ASJC) codes

  • 土木與結構工程
  • 建築與營造
  • 污染
  • 機械工業
  • 工業與製造工程
  • 電氣與電子工程

指紋

深入研究「SiO<sub>2</sub>-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH<sub>4</sub> (sodium borohydride) solution」主題。共同形成了獨特的指紋。

引用此