Stereoelectronic effect of curved aromatic structures: Favoring the unexpected endo conformation of benzylic-substituted sumanene

Shuhei Higashibayashi, Satoru Onogi, Hemant Kumar Srivastava, G. Narahari Sastry, Yao-Ting Wu, Hidehiro Sakurai

研究成果: Article

23 引文 斯高帕斯(Scopus)

摘要

Throwing a curve: The first example of a through-bond stereoelectronic effect for curved aromatic compounds is described for buckybowls, that is, benzylic-substituted sumanenes. Methyl- and hydroxysumanene favor the endo-R conformer because of a difference in the strength, between the conformers, of the hyperconjugation of the benzylic C-H bond with the bowl.

原文English
頁(從 - 到)7314-7316
頁數3
期刊Angewandte Chemie - International Edition
52
發行號28
DOIs
出版狀態Published - 2013 七月 8

    指紋

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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