Strontium oxide deposited onto a load-bearable and porous titanium matrix as dynamic and high-surface-contact-area catalysis for transesterification

Han Lee, Jiunn Der Liao, Mu Hsuan Lee, Bernard Haochih Liu, Wei En Fu, Kundan Sivashanmugan, Yung Der Juang

研究成果: Article

摘要

Strontium oxide (SrO) deposited onto a porous titanium (Ti)-based scaffold (P-Ti) is a promising and novel approach for high-throughput transesterification. Notably, a highly porous and calcinated scaffold provides a load-bearable support for a continuous process, while the calcinated SrO catalyst, as it is well distributed inside the porous matrix, can extend its surface contact area with the reactant. In this work, the formation of transesterification reaction with the conversion and production of olive oil to biodiesel inside the porous matrix is particularly examined. The as-designed SrO-coated porous titanium (Ti)-based scaffold with 55% porosity was prepared via a hydrothermal procedure, followed by a dip coating method. Mechanical tests of samples were conducted by a nanoindentator, whereas the physical and chemical structures were identified by IR and Raman Spectroscopies. The results implied that SrO catalysts can be firmly deposited onto a load-bearable, highly porous matrix and play an effective role for the transesterification reaction with the oil mass. It is promising to be employed as a load-bearable support for a continuous transesterification process, such as a process for batch or continuous biodiesel production, under an efficient heating source by a focused microwave system.

原文English
文章編號973
期刊Nanomaterials
8
發行號12
DOIs
出版狀態Published - 2018 十二月

指紋

Strontium
Transesterification
Titanium
Oxides
Catalysis
Scaffolds
Biofuels
Biodiesel
Olive oil
Catalysts
Raman spectroscopy
Infrared spectroscopy
Oils
Porosity
Microwaves
Throughput
Heating
Coatings

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Materials Science(all)

引用此文

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title = "Strontium oxide deposited onto a load-bearable and porous titanium matrix as dynamic and high-surface-contact-area catalysis for transesterification",
abstract = "Strontium oxide (SrO) deposited onto a porous titanium (Ti)-based scaffold (P-Ti) is a promising and novel approach for high-throughput transesterification. Notably, a highly porous and calcinated scaffold provides a load-bearable support for a continuous process, while the calcinated SrO catalyst, as it is well distributed inside the porous matrix, can extend its surface contact area with the reactant. In this work, the formation of transesterification reaction with the conversion and production of olive oil to biodiesel inside the porous matrix is particularly examined. The as-designed SrO-coated porous titanium (Ti)-based scaffold with 55{\%} porosity was prepared via a hydrothermal procedure, followed by a dip coating method. Mechanical tests of samples were conducted by a nanoindentator, whereas the physical and chemical structures were identified by IR and Raman Spectroscopies. The results implied that SrO catalysts can be firmly deposited onto a load-bearable, highly porous matrix and play an effective role for the transesterification reaction with the oil mass. It is promising to be employed as a load-bearable support for a continuous transesterification process, such as a process for batch or continuous biodiesel production, under an efficient heating source by a focused microwave system.",
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AU - Lee, Han

AU - Liao, Jiunn Der

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AU - Liu, Bernard Haochih

AU - Fu, Wei En

AU - Sivashanmugan, Kundan

AU - Juang, Yung Der

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