Synthesis and characterization of phase pure and Mg-modified AgZnVO4 microwave dielectrics for high-frequency ULTCC applications

Cheng Liang Huang, Yi Lun Hsieh, I. Chun Ling, Tsung Hsien Hsu

研究成果: Article同行評審

8 引文 斯高帕斯(Scopus)

摘要

A novel low-loss and ultra-low temperature sinterable microwave dielectric material, AgZnVO4, was systematically investigated for the first time. The material exhibited a monoclinic structure with a space group P21/n, obtained by conventional solid-state processing. The material also showed combined microwave dielectric properties of εr = 10.3, Q×f = 42,000 GHz, and τf = –9.2 ppm/°C for specimens sintered at 540 °C. The partial substitution of Mg for Zn in the Ag(Zn1−xMgx)VO4 ceramics effectively improved the densification and reduced the dielectric loss of the ceramics. X-ray diffraction patterns revealed a single solid solution phase of Ag(Zn1−xMgx)VO4. The relative density, dielectric polarizability, packing fraction, lattice energy, and bond valence of the samples were calculated. An excellent combination of the microwave dielectric properties was obtained for Ag(Zn0.97Mg0.03)VO4 ceramic sintered at 540 °C: εr = 10.6, Q×f = 52,000 GHz, and τf = –10 ppm/°C. Additionally, the ceramic exhibited good chemical compatibility with aluminum electrodes, indicating great potential for ultra-low temperature co-fired ceramics (ULTCC) applications, particularly in the microwave and millimeter wave regions.

原文English
文章編號169890
期刊Journal of Alloys and Compounds
949
DOIs
出版狀態Published - 2023 7月 15

All Science Journal Classification (ASJC) codes

  • 材料力學
  • 機械工業
  • 金屬和合金
  • 材料化學

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