Synthesis and solvatochromism of soluble polyethers containing isolated emissive p-aryl vinylene derivatives

Shiao Wen Hwang, Yun Chen

研究成果: Article同行評審

7 引文 斯高帕斯(Scopus)

摘要

Two soluble polyethers (ηred>0.4 dL/g) consisting of isolated emissive p-aryl vinylene derivatives have been synthesized and characterized. The introductions of ether linkages and aliphatic chains result in enhanced solubility in common organic solvents such as tetrahydrofuran (THF) and chloroform. The polyethers exhibit good thermal stability with onset decomposition temperatures at around 400 °C in nitrogen. The photoluminescence spectra of the two polyethers show a maximum peaks at 446 and 394 nm, respectively. The shifts of the photoluminescence maxima are controlled by the steric conformation of the emissive chromophores. On the other part, an interesting solvatochromism of three polyethers was observed in solution. The absorption maxima of dilute polymeric solutions exhibit bathochromism at first, and then hypsochromism with increasing solvent polarity. This may be due to the alteration of the electronic structure in these emissive polyethers.

原文English
頁(從 - 到)1311-1317
頁數7
期刊Journal of Polymer Science, Part A: Polymer Chemistry
38
發行號8
DOIs
出版狀態Published - 2000 4月 15

All Science Journal Classification (ASJC) codes

  • 聚合物和塑料
  • 有機化學
  • 材料化學

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