Synthesis of chiral polymers containing dimethylaminobornanol moieties

研究成果: Article同行評審

4 引文 斯高帕斯(Scopus)

摘要

In order to investigate the influence of spacer on the stereoselectivity of the addition of n‐butyllithium to aldehydes, three kinds of chiral polymers containing dimethylaminobornanol moieties were synthesized. The polymerization of the chiral monomers was carried out under various conditions. Cross‐linked chiral polymers were prepared by copolymerization of the chiral monomers with commercial p‐divinyl benzene. The conversion was found to be affected by the kind of solvents. Asymmetric addition of n‐butyllithium to benzaldehyde was carried out in the presence of the chiral polymers having dimethylaminobornanol moieties, and it was found that all three kinds of chiral polymers are effective for the asymmetric addition. Advantages of insoluble chiral polymers such as the ease of separation from products and the ability to be recycled, are discussed.

原文English
頁(從 - 到)35-44
頁數10
期刊Die Angewandte Makromolekulare Chemie
164
發行號1
DOIs
出版狀態Published - 1988 十二月

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

指紋 深入研究「Synthesis of chiral polymers containing dimethylaminobornanol moieties」主題。共同形成了獨特的指紋。

引用此