Synthetic and structural considerations on highly curved bowl-shaped fragments of fullerenes

Yao Ting Wu, Tsun Cheng Wu, Min Kuan Chen, Hsin Ju Hsin

研究成果: Article

13 引文 斯高帕斯(Scopus)

摘要

Numerous highly curved fragments of C60 and unique subunits of C70 were synthesized under mild conditions using metal-catalyzed protocols. According to X-ray crystallographic analyses, highly curved fragments of C60 have a maximum π-orbital axis vector (POAV) pyramidalization angle of up to 12.9°, whereas distinctive fragments of C70, analogous to the tube portion of the rugby-shaped buckyball, are less curved. Among the eight buckybowls studied herein, five form polar crystals. Depending on the molecular geometry, the inversion dynamics of buckybowls involves either a planar or an S-shaped (non-planar) transition structure.

原文English
頁(從 - 到)539-544
頁數6
期刊Pure and Applied Chemistry
86
發行號4
DOIs
出版狀態Published - 2014 四月 17

    指紋

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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