Synthetic green fluorescent protein chromophore analogues with a positive charge at the phenyl-like group

Zhao Yi Zhang; Robert Sung; Kuangsen Sung

doi:10.1007/s00726-017-2500-8

Synthetic green fluorescent protein chromophore analogues with a positive charge at the phenyl-like group

Zhao Yi Zhang, Robert Sung, Kuangsen Sung

化學系

研究成果: Article › 同行評審

4 引文斯高帕斯（Scopus）

摘要

Synthetic green fluorescent protein (GFP) chromophore analogues with a positive charge at the phenyl-like group have the highly electrophilic amidine carbon, smaller LUMO–HOMO energy gap, red-shifted electronic absorptions and fluorescent emissions, and accelerated E-Z thermoisomerization rates. They are water-labile and their hydrolysis results in ring-opening of the imidazolinone moiety with a half life around 25–37 h in D₂O at 25 °C.

原文	English
頁（從 - 到）	141-147
頁數	7
期刊	Amino Acids
卷	50
發行號	1
DOIs	https://doi.org/10.1007/s00726-017-2500-8
出版狀態	Published - 2018 1月 1

All Science Journal Classification (ASJC) codes

生物化學
臨床生物化學
有機化學

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10.1007/s00726-017-2500-8

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abstract = "Synthetic green fluorescent protein (GFP) chromophore analogues with a positive charge at the phenyl-like group have the highly electrophilic amidine carbon, smaller LUMO–HOMO energy gap, red-shifted electronic absorptions and fluorescent emissions, and accelerated E-Z thermoisomerization rates. They are water-labile and their hydrolysis results in ring-opening of the imidazolinone moiety with a half life around 25–37 h in D2O at 25 °C.",

author = "Zhang, {Zhao Yi} and Robert Sung and Kuangsen Sung",

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AU - Sung, Kuangsen

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AB - Synthetic green fluorescent protein (GFP) chromophore analogues with a positive charge at the phenyl-like group have the highly electrophilic amidine carbon, smaller LUMO–HOMO energy gap, red-shifted electronic absorptions and fluorescent emissions, and accelerated E-Z thermoisomerization rates. They are water-labile and their hydrolysis results in ring-opening of the imidazolinone moiety with a half life around 25–37 h in D2O at 25 °C.

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ER -

Synthetic green fluorescent protein chromophore analogues with a positive charge at the phenyl-like group

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