TY - JOUR
T1 - Tetra-butyl-ammonium bis-[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H- 4,2,1-benzothiaza-siline-1,1-diyl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetrasolvate
AU - Tsai, Yi Fang
AU - Hsu, Hua Fen
AU - Hsu, Kuei Fang
AU - Wang, Ju Chun
PY - 2010
Y1 - 2010
N2 - In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.
AB - In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.
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U2 - 10.1107/S1600536810022014
DO - 10.1107/S1600536810022014
M3 - Article
C2 - 21587755
AN - SCOPUS:77954399789
VL - 66
SP - m844
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 7
ER -