The absorption kinetics of no from flue gas in a stirred tank reactor with KMnO4/NaOH solutions

H. Chu, S. Y. Li, T. W. Chien

研究成果: Article

38 引文 斯高帕斯(Scopus)

摘要

Absorptions of NO by neutral and alkaline solutions of KMnO4 were performed in this study to clarify the reaction kinetics. The experiments were mainly carried out under 50 °C, which is the common operating temperature for wet scrubbers. According to the assumption that the absorption of NO was developed under the fast pseudo-mth reaction regime, which is verified in the experiments, the absorption rate of NO into KMnO4 solutions is found to be negative half-order dependent on PNO and first-order dependent on [KMnO4]. The addition of NaOH into the solutions of KMnO4 would increase the absorption rate of NO. The absorption rate of NO at 25 °C is lower than that of 50 °C. In the ranges of this study, the absorption rate of NO would not change by changing the gas flow rate and O2 concentration. NO2- is the dominate ion in the liquid phase for this study. However, the [NO3-]/[NO2-] ratio increases with the increasing NaOH concentration.

原文English
頁(從 - 到)801-827
頁數27
期刊Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering
33
發行號5
DOIs
出版狀態Published - 1998 一月 1

All Science Journal Classification (ASJC) codes

  • Environmental Engineering

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