@article{3f319c55717c44cca4550da37b0f3504,
title = "The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; Nitrite reduction mediated by a V(iii) complex",
abstract = "A V(iii) complex bearing a tris(thiolato)phoshine derivative mediates the reduction of nitrite without the assistance of external protons or oxophilic substrates. The metal site plays dual roles for nitrite binding and deoxygenation. The reaction is monitored by spectroscopy combined with isotopic labeling experiments. The formed product, a {VNO}4 species, is isolated and characterized. This journal is ",
author = "Pan, {Hung Ruei} and Wu, {Zong Han} and Kuo, {Chin Ting} and Ou, {Han Jang} and Lee, {Gene Hsiang} and Hsu, {Hua Fen}",
note = "Funding Information: This work was supported by the Ministry of Science and Technology (MOST 108-2113-M-006-001) and National Cheng Kung University in Taiwan. We thank Mr Ming-Feng Chen and Mr Tsung-Lun Kan from the Establishment of the Instrument Development Center at the National Cheng Kung University for assisting the measurements of ESI-MS data and NMR data.",
year = "2020",
month = nov,
day = "7",
doi = "10.1039/d0dt03274c",
language = "English",
volume = "49",
pages = "14393--14396",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "41",
}