The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; Nitrite reduction mediated by a V(iii) complex

Hung Ruei Pan, Zong Han Wu, Chin Ting Kuo, Han Jang Ou, Gene Hsiang Lee, Hua Fen Hsu

研究成果: Article同行評審

摘要

A V(iii) complex bearing a tris(thiolato)phoshine derivative mediates the reduction of nitrite without the assistance of external protons or oxophilic substrates. The metal site plays dual roles for nitrite binding and deoxygenation. The reaction is monitored by spectroscopy combined with isotopic labeling experiments. The formed product, a {VNO}4 species, is isolated and characterized. This journal is

原文English
頁(從 - 到)14393-14396
頁數4
期刊Dalton Transactions
49
發行號41
DOIs
出版狀態Published - 2020 十一月 7

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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