The First Example of a Seven-Coordinate Vanadium(III) Thiolate Complex Containing the Hydrazine Molecule, an Intermediate of Nitrogen Fixation

Hua-Fen Hsu, Wei Cheng Chu, Chen Hsiung Hung, Ju Hsiou Liao

研究成果: Article同行評審

23 引文 斯高帕斯(Scopus)

摘要

The first example of a seven-coordinate vanadium(III) thiolate complex, [V(PS3″)(N2H4)3] (1), where PS3″ = [P(C6H3-3-Me3Si-2-S)3] 3-, has been synthesized and characterized. Compound 1 contains a tetradentate ligand (PS3″) and three hydrazine molecules, forming a capped octahedral geometry. A five-coordinate vanadium(III) complex, [V(PS3)(1-Me-Im) (2), where PS3 = [P(C6H4-2-S) 3]3- and 1-Me-Im = 1-methyl-imidazole was also obtained. Compound 2 adopts a trigonal bipyramidal geometry, in which the vanadium is ligated by the title ligand, PS3, and one 1-Me-Im molecule.

原文English
頁(從 - 到)7369-7371
頁數3
期刊Inorganic Chemistry
42
發行號23
DOIs
出版狀態Published - 2003 十一月 17

All Science Journal Classification (ASJC) codes

  • 物理與理論化學
  • 無機化學

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