The indirect synthesized method induced relaxor state to ferroelectric characteristics for Pb 0.95La 0.05(Fe 2/3W 1/3) 0.65Ti 0.35O 3 ceramics

Cheng Shong Hong, Sheng Yuan Chu, Cheng Che Tsai, Chi Cheng Hsu

研究成果: Article

2 引文 斯高帕斯(Scopus)

摘要

Pb 0.95La 0.05(Fe 2/3W 1/3) 0.65Ti 0.35O 3 ceramics are synthesized by using the conventional direct oxide synthesized (DS) method and the indirect synthesized (IS) method. The low-field dielectric response is investigated by using the empirical law, two ordering models and the space charge polarization. The temperature-dependent dielectric peak of the samples prepared using the IS synthesized method is obviously increased; the temperature-dielectric constant is changed to sharp and the diffused phase characteristic is decreased. It is concluded that the IS synthesized method can change the dielectric natures from a relaxor like behavior to a sharp ferroelectric state. The space charge polarization is also changed by using the IS synthesized method. According to these results, it is suggested that the 1:1 ordered domain is enhanced based on the random-site type by using the IS synthesized method for Pb 0.95La 0.05(Fe 2/3W 1/3) 0.65Ti 0.35O 3 ceramics. However, if the sintering temperature is not high enough for some calcined powders, the random-site type can be changed to the space charge type.

原文English
頁(從 - 到)4123-4130
頁數8
期刊Ceramics International
38
發行號5
DOIs
出版狀態Published - 2012 七月 1

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

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