TY - JOUR
T1 - The kinetics of catalytic incineration of dimethyl sulfide and dimethyl disulfide over an MnO/Fe
AU - Chu, Hsin
AU - Hao, Guang Huei
AU - Tseng, Ting Ke
PY - 2001/4
Y1 - 2001/4
N2 - The catalytic incineration of dimethyl sulfide and dimethyl disulfide [(CH3)2S and (CH3)2S2] over an MnO/Fe2O3 catalyst was carried out in a bench-scale catalytic incinerator. Three kinetic models (i.e., the power-rate law, the Mars and Van Krevelen model, and the Langmuir-Hinshelwood model) were used to analyze the results. A differential reactor design was used for best fit of kinetic models in this study. The results show that the Langmuir-Hinshelwood model may be feasible to describe the catalytic incineration of (CH3)2S and (CH3)2S2. This suggests that the chemical adsorption of O2 molecules is important in this incineration.
AB - The catalytic incineration of dimethyl sulfide and dimethyl disulfide [(CH3)2S and (CH3)2S2] over an MnO/Fe2O3 catalyst was carried out in a bench-scale catalytic incinerator. Three kinetic models (i.e., the power-rate law, the Mars and Van Krevelen model, and the Langmuir-Hinshelwood model) were used to analyze the results. A differential reactor design was used for best fit of kinetic models in this study. The results show that the Langmuir-Hinshelwood model may be feasible to describe the catalytic incineration of (CH3)2S and (CH3)2S2. This suggests that the chemical adsorption of O2 molecules is important in this incineration.
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U2 - 10.1080/10473289.2001.10464288
DO - 10.1080/10473289.2001.10464288
M3 - Article
C2 - 11321914
AN - SCOPUS:0034944367
SN - 1096-2247
VL - 51
SP - 574
EP - 581
JO - Journal of the Air and Waste Management Association
JF - Journal of the Air and Waste Management Association
IS - 4
ER -