The radical reactions of imine radicals produced from the metal salts oxidation of 2-amino-1,4-benzoquinones

Po Yuan Lu, Kuang Po Chen, Che Ping Chuang

研究成果: Article同行評審

4 引文 斯高帕斯(Scopus)

摘要

The metal salts mediated oxidative free radical reaction of 2-amino-1,4-benzoquinones is described. Imine radicals can be generated by the oxidation of 2-amino-1,4-benzoquinones with Mn(III) and Ag(II). The dimeric products 4 and 14 were formed via the intermolecular radical coupling reaction of the corresponding radical intermediates 5 and 15. In the presence of styrene, twistane 17 was afforded from 2-phenylamino-1,4-benzoquinone 1 via a radical annulation reaction of imine radical 5.

原文English
頁(從 - 到)7415-7421
頁數7
期刊Tetrahedron
65
發行號36
DOIs
出版狀態Published - 2009 九月 5

All Science Journal Classification (ASJC) codes

  • 生物化學
  • 藥物發現
  • 有機化學

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