Theoretical study of the Wanzlick equilibrium

Mu-Jeng Cheng, Chun Liang Lai, Ching Han Hu

研究成果: Article

10 引文 (Scopus)

摘要

A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

原文English
頁（從 - 到）2617-2621
頁數5
期刊Molecular Physics
卷102
發行號23-24
DOIs
出版狀態Published - 2004 十二月 10

指紋

Theoretical Models
imidazoles
dissociation

All Science Journal Classification (ASJC) codes

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

引用此文

Cheng, Mu-Jeng ; Lai, Chun Liang ; Hu, Ching Han. / Theoretical study of the Wanzlick equilibrium. 於: Molecular Physics. 2004 ; 卷 102, 編號 23-24. 頁 2617-2621.
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Cheng, M-J, Lai, CL & Hu, CH 2004, 'Theoretical study of the Wanzlick equilibrium', Molecular Physics, 卷 102, 編號 23-24, 頁 2617-2621. https://doi.org/10.1080/00268970412331292911

Theoretical study of the Wanzlick equilibrium. / Cheng, Mu-Jeng; Lai, Chun Liang; Hu, Ching Han.

於: Molecular Physics, 卷 102, 編號 23-24, 10.12.2004, p. 2617-2621.

研究成果: Article

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N2 - A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

AB - A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

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Cheng M-J, Lai CL, Hu CH. Theoretical study of the Wanzlick equilibrium. Molecular Physics. 2004 12月 10;102(23-24):2617-2621. https://doi.org/10.1080/00268970412331292911

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