Theoretical study of the Wanzlick equilibrium

Mu Jeng Cheng, Chun Liang Lai, Ching Han Hu

研究成果: Article同行評審

11 引文 斯高帕斯(Scopus)

摘要

A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

原文English
頁(從 - 到)2617-2621
頁數5
期刊Molecular Physics
102
發行號23-24
DOIs
出版狀態Published - 2004 12月 10

All Science Journal Classification (ASJC) codes

  • 生物物理學
  • 分子生物學
  • 凝聚態物理學
  • 物理與理論化學

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