摘要
A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.
原文 | English |
---|---|
頁(從 - 到) | 2617-2621 |
頁數 | 5 |
期刊 | Molecular Physics |
卷 | 102 |
發行號 | 23-24 |
DOIs | |
出版狀態 | Published - 2004 12月 10 |
All Science Journal Classification (ASJC) codes
- 生物物理學
- 分子生物學
- 凝聚態物理學
- 物理與理論化學