Theoretical study of the Wanzlick equilibrium

Mu Jeng Cheng; Chun Liang Lai; Ching Han Hu

doi:10.1080/00268970412331292911

Theoretical study of the Wanzlick equilibrium

Mu Jeng Cheng, Chun Liang Lai, Ching Han Hu

化學系

研究成果: Article › 同行評審

11 引文斯高帕斯（Scopus）

摘要

A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

原文	English
頁（從 - 到）	2617-2621
頁數	5
期刊	Molecular Physics
卷	102
發行號	23-24
DOIs	https://doi.org/10.1080/00268970412331292911
出版狀態	Published - 2004 12月 10

All Science Journal Classification (ASJC) codes

生物物理學
分子生物學
凝聚態物理學
物理與理論化學

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10.1080/00268970412331292911

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abstract = "A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.",

author = "Cheng, {Mu Jeng} and Lai, {Chun Liang} and Hu, {Ching Han}",

note = "Funding Information: This work was supported by the National Science Council of Taiwan, Republic of China. We thank the National Center for High-performance Computing for computer time and facilities.",

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T1 - Theoretical study of the Wanzlick equilibrium

AU - Cheng, Mu Jeng

AU - Lai, Chun Liang

AU - Hu, Ching Han

N1 - Funding Information: This work was supported by the National Science Council of Taiwan, Republic of China. We thank the National Center for High-performance Computing for computer time and facilities.

PY - 2004/12/10

Y1 - 2004/12/10

N2 - A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

AB - A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.

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DO - 10.1080/00268970412331292911

M3 - Article

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SP - 2617

EP - 2621

JO - Molecular Physics

JF - Molecular Physics

SN - 0026-8976

IS - 23-24

ER -

Theoretical study of the Wanzlick equilibrium

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