Thermal and spectroscopy studies on ternary miscibility and phase behavior in blends comprising poly(4-Vinyl phenol) and two aryl polyesters

L. I.Ting Lee, Eamor M. Woo

研究成果: Article同行評審

11 引文 斯高帕斯(Scopus)

摘要

Thermal analysis and Fourier transform infrared spectroscopy characterizations were performed on three ternary blend systems that comprise poly(4-vinyl phenol) (PVPh) and any two of the three homologous aryl polyesters [poly(ethylene terephthalate) (PET), poly(trimethylene terephthalate) (PTT), and poly(butylene terephthalate) (PBT)]. Although PVPh is miscible with any one of the polyesters in forming a binary blend system, miscibility in ternary systems by introducing one more polymer of different structures to the blend system is not always expected. However, this study concludes that miscibility does exist in all these three ternary blends of all compositions investigated. Reasons and factors for such behavior were probed. Quantitative interactions in the ternary blend system were also estimated. The overall interaction energy density (B) by analysis of melting point depression for the PBT/PVPh/PET ternary blend system led to a negative value (B = -5.74 cal/ cm3). Similarly, T g-composition analyses were performed on two other ternary blend systems, PET/PVPh/PTT and PTT/PVPh/PBT. Comparison of the qualitative results showed that the interaction energy densities in the other two ternary blend systems are similarly negative and comparable to the PBT/PVPh/PET ternary blend system. The Fourier transform infrared spectroscopy results also support the qualitative findings among these three ternary blend systems.

原文English
頁(從 - 到)1339-1350
頁數12
期刊Journal of Polymer Science, Part B: Polymer Physics
44
發行號9
DOIs
出版狀態Published - 2006 五月 1

All Science Journal Classification (ASJC) codes

  • 凝聚態物理學
  • 物理與理論化學
  • 聚合物和塑料
  • 材料化學

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