TiCl 4-catalyzed synthesis of peroxyacetals from aldehydes

Chen Yu Tsai, Lu An Chen, Kuangsen Sung

研究成果: Article同行評審

1 引文 斯高帕斯(Scopus)

摘要

Peroxyacetals 2a-2j were prepared by TiCl 4-promoted nucleophilic addition of both tert-butyl hydroperoxide (TBHP) and an alcohol to the corresponding aldehyde. The reaction works well with a variety of aldehydes, but not with ketones. The magnitude of the equilibrium constant for hemiacetal formation plays an important role; a large constant enables high conversion to peroxyacetal.

原文English
頁(從 - 到)321-325
頁數5
期刊Canadian Journal of Chemistry
90
發行號4
DOIs
出版狀態Published - 2012 四月 1

All Science Journal Classification (ASJC) codes

  • 催化
  • 化學 (全部)
  • 有機化學

指紋

深入研究「TiCl <sub>4</sub>-catalyzed synthesis of peroxyacetals from aldehydes」主題。共同形成了獨特的指紋。

引用此