Transcrystallization of PTFE fiber/PP composites (I) crystallization kinetics and morphology

Chi Wang, L. M. Hwang

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74 引文 斯高帕斯(Scopus)

摘要

Transcrystallization of polypropylene (PP) on the polytetranuoroethylene (PTFE) fiber was investigated. Both nucleation rate and crystal growth rate were determined by a polarized optical microscope. Based on the theory of heterogeneous nucleation, it has been found that the induction time can correlate well with the nucleation rate in determining the interfacial free energy difference function Δσ. The ratio of Δσ in the bulk matrix to that at the interface is 1.63 which implies the transcrystalline growth is favorable from a thermodynamic point of view. No difference in crystal growth rate of PP has been found in either spherulites or transcrystalline layers. On the basis of regime theory, a transition between regimes II and III was observed at ΔT = 48K. From the morphology studies, it has been found that the thickness of the transcrystalline layer increases with crystallization temperature, from 30 to 120 μm in the temperature range of 110-140°C. The growth of transcrystalline layer is hindered by the spherulites nucleated in the bulk. Moreover, the radius of spherulites adjacent to the transcrystalline layer is much smaller than that distant to the fiber. No significant increase in nucleation density at fiber ends is observed. Effect of internal stresses of fibers on the fiber's nucleating ability is not pronounced.

原文English
頁(從 - 到)47-56
頁數10
期刊Journal of Polymer Science, Part B: Polymer Physics
34
發行號1
DOIs
出版狀態Published - 1996 一月 15

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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