Transition-Metal Dichalcogenide NiTe2: An Ambient-Stable Material for Catalysis and Nanoelectronics

Silvia Nappini; Danil W. Boukhvalov; Gianluca D'Olimpio; Libo Zhang; Barun Ghosh; Chia Nung Kuo; Haoshan Zhu; Jia Cheng; Michele Nardone; Luca Ottaviano; Debashis Mondal; Raju Edla; Jun Fuji; Chin Shan Lue; Ivana Vobornik; Jory A. Yarmoff; Amit Agarwal; Lin Wang; Lixue Zhang; Federica Bondino; Antonio Politano

doi:10.1002/adfm.202000915

Transition-Metal Dichalcogenide NiTe₂: An Ambient-Stable Material for Catalysis and Nanoelectronics

Silvia Nappini, Danil W. Boukhvalov, Gianluca D'Olimpio, Libo Zhang, Barun Ghosh, Chia Nung Kuo, Haoshan Zhu, Jia Cheng, Michele Nardone, Luca Ottaviano, Debashis Mondal, Raju Edla, Jun Fuji, Chin Shan Lue, Ivana Vobornik, Jory A. Yarmoff, Amit Agarwal, Lin Wang, Lixue Zhang, Federica BondinoAntonio Politano

物理學系

研究成果: Article › 同行評審

41 引文斯高帕斯（Scopus）

摘要

By means of theory and experiments, the application capability of nickel ditelluride (NiTe₂) transition-metal dichalcogenide in catalysis and nanoelectronics is assessed. The Te surface termination forms a TeO₂ skin in an oxygen environment. In ambient atmosphere, passivation is achieved in less than 30 min with the TeO₂ skin having a thickness of about 7 Å. NiTe₂ shows outstanding tolerance to CO exposure and stability in water environment, with subsequent good performance in both hydrogen and oxygen evolution reactions. NiTe₂-based devices consistently demonstrate superb ambient stability over a timescale as long as one month. Specifically, NiTe₂ has been implemented in a device that exhibits both superior performance and environmental stability at frequencies above 40 GHz, with possible applications as a receiver beyond the cutoff frequency of a nanotransistor.

原文	English
文章編號	2000915
期刊	Advanced Functional Materials
卷	30
發行號	22
DOIs	https://doi.org/10.1002/adfm.202000915
出版狀態	Published - 2020 5月 1

All Science Journal Classification (ASJC) codes

化學 (全部)
材料科學(全部)
凝聚態物理學

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10.1002/adfm.202000915

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Nappini, S., Boukhvalov, D. W., D'Olimpio, G., Zhang, L., Ghosh, B., Kuo, C. N., Zhu, H., Cheng, J., Nardone, M., Ottaviano, L., Mondal, D., Edla, R., Fuji, J., Lue, C. S., Vobornik, I., Yarmoff, J. A., Agarwal, A., Wang, L., Zhang, L., ... Politano, A. (2020). Transition-Metal Dichalcogenide NiTe₂: An Ambient-Stable Material for Catalysis and Nanoelectronics. Advanced Functional Materials, 30(22), Article 2000915. https://doi.org/10.1002/adfm.202000915

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title = "Transition-Metal Dichalcogenide NiTe2: An Ambient-Stable Material for Catalysis and Nanoelectronics",

abstract = "By means of theory and experiments, the application capability of nickel ditelluride (NiTe2) transition-metal dichalcogenide in catalysis and nanoelectronics is assessed. The Te surface termination forms a TeO2 skin in an oxygen environment. In ambient atmosphere, passivation is achieved in less than 30 min with the TeO2 skin having a thickness of about 7 {\AA}. NiTe2 shows outstanding tolerance to CO exposure and stability in water environment, with subsequent good performance in both hydrogen and oxygen evolution reactions. NiTe2-based devices consistently demonstrate superb ambient stability over a timescale as long as one month. Specifically, NiTe2 has been implemented in a device that exhibits both superior performance and environmental stability at frequencies above 40 GHz, with possible applications as a receiver beyond the cutoff frequency of a nanotransistor.",

author = "Silvia Nappini and Boukhvalov, {Danil W.} and Gianluca D'Olimpio and Libo Zhang and Barun Ghosh and Kuo, {Chia Nung} and Haoshan Zhu and Jia Cheng and Michele Nardone and Luca Ottaviano and Debashis Mondal and Raju Edla and Jun Fuji and Lue, {Chin Shan} and Ivana Vobornik and Yarmoff, {Jory A.} and Amit Agarwal and Lin Wang and Lixue Zhang and Federica Bondino and Antonio Politano",

note = "Publisher Copyright: {\textcopyright} 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2020",

month = may,

day = "1",

doi = "10.1002/adfm.202000915",

language = "English",

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Nappini, S, Boukhvalov, DW, D'Olimpio, G, Zhang, L, Ghosh, B, Kuo, CN, Zhu, H, Cheng, J, Nardone, M, Ottaviano, L, Mondal, D, Edla, R, Fuji, J, Lue, CS, Vobornik, I, Yarmoff, JA, Agarwal, A, Wang, L, Zhang, L, Bondino, F & Politano, A 2020, 'Transition-Metal Dichalcogenide NiTe₂: An Ambient-Stable Material for Catalysis and Nanoelectronics', Advanced Functional Materials, 卷 30, 編號 22, 2000915. https://doi.org/10.1002/adfm.202000915

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T1 - Transition-Metal Dichalcogenide NiTe2

T2 - An Ambient-Stable Material for Catalysis and Nanoelectronics

AU - Nappini, Silvia

AU - Boukhvalov, Danil W.

AU - D'Olimpio, Gianluca

AU - Zhang, Libo

AU - Ghosh, Barun

AU - Kuo, Chia Nung

AU - Zhu, Haoshan

AU - Cheng, Jia

AU - Nardone, Michele

AU - Ottaviano, Luca

AU - Mondal, Debashis

AU - Edla, Raju

AU - Fuji, Jun

AU - Lue, Chin Shan

AU - Vobornik, Ivana

AU - Yarmoff, Jory A.

AU - Agarwal, Amit

AU - Wang, Lin

AU - Zhang, Lixue

AU - Bondino, Federica

AU - Politano, Antonio

PY - 2020/5/1

Y1 - 2020/5/1

N2 - By means of theory and experiments, the application capability of nickel ditelluride (NiTe2) transition-metal dichalcogenide in catalysis and nanoelectronics is assessed. The Te surface termination forms a TeO2 skin in an oxygen environment. In ambient atmosphere, passivation is achieved in less than 30 min with the TeO2 skin having a thickness of about 7 Å. NiTe2 shows outstanding tolerance to CO exposure and stability in water environment, with subsequent good performance in both hydrogen and oxygen evolution reactions. NiTe2-based devices consistently demonstrate superb ambient stability over a timescale as long as one month. Specifically, NiTe2 has been implemented in a device that exhibits both superior performance and environmental stability at frequencies above 40 GHz, with possible applications as a receiver beyond the cutoff frequency of a nanotransistor.

AB - By means of theory and experiments, the application capability of nickel ditelluride (NiTe2) transition-metal dichalcogenide in catalysis and nanoelectronics is assessed. The Te surface termination forms a TeO2 skin in an oxygen environment. In ambient atmosphere, passivation is achieved in less than 30 min with the TeO2 skin having a thickness of about 7 Å. NiTe2 shows outstanding tolerance to CO exposure and stability in water environment, with subsequent good performance in both hydrogen and oxygen evolution reactions. NiTe2-based devices consistently demonstrate superb ambient stability over a timescale as long as one month. Specifically, NiTe2 has been implemented in a device that exhibits both superior performance and environmental stability at frequencies above 40 GHz, with possible applications as a receiver beyond the cutoff frequency of a nanotransistor.

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JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 22

M1 - 2000915

ER -

Transition-Metal Dichalcogenide NiTe2: An Ambient-Stable Material for Catalysis and Nanoelectronics

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Transition-Metal Dichalcogenide NiTe₂: An Ambient-Stable Material for Catalysis and Nanoelectronics