Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and...

Ann R. Schake, Hui Lien Tsai, Nadine De Vries, Robert J. Webb, Kirsten Folting, David N. Hendrickson, George Christou

研究成果: Article

54 引文 斯高帕斯(Scopus)

摘要

Title full: Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] ·H2O. As a means of varying the electron count of complexes [Mn 12O12(O2CR)16(H2O) 4](1; R = Me or Ph), the aggregates [Mn8Fe 4O12(O2CMe)16(H2O) 4] 2 and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] 3 have been prepared; magnetochemical measurements confirm that the unusual of properties 1 can be significantly altered by 'conversion' to 2 and 3.

原文English
頁(從 - 到)181-183
頁數3
期刊Journal of the Chemical Society, Chemical Communications
發行號2
DOIs
出版狀態Published - 1992 十二月 1

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

指紋 深入研究「Variation in the electron count and ground state of [Mn<sub>12</sub>O <sub>12</sub>(O<sub>2</sub>CR)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn<sub>8</sub>Fe<sub>4</sub>O<sub>12</sub>(O<sub>2</sub>CMe) <sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>]·4H<sub>2</sub>O· 2MeCO<sub>2</sub>H and...」主題。共同形成了獨特的指紋。

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